|
|
S-adenosyl-L-methionine + 4-hydroxyglucobrassicin <=> 4-methoxyindol-3-ylmethyl-glucosinolate + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-2163
|
|
|
|
glucobrassicin + H2O <=> indol-3-yl-acetothiohydroxamate-O-sulfonate + D-glucose + H+
|
3.2.1.147
thioglucosidase
|
–
|
| |
MetaCyc:
RXN-1444
|
|
|
|
4-methoxyindol-3-ylmethyl-glucosinolate + H2O <=> 4-methoxy-3-indolylmethyl_glucosinolate_aglycone + D-glucose + H+
|
3.2.1.147
thioglucosidase
|
–
|
| |
MetaCyc:
RXNQT-4359
|
|
|
|
indol-3-ylmethylisothiocyanate-[gamma-Glu-Cys} + H2O <=> indol-3-ylmethylisothiocyanate-L-cysteine + L-glutamate
|
3.4.19.13
glutathione gamma-glutamate hydrolase
|
–
|
| |
MetaCyc:
RXN-19574
|
|
|
|
glucobrassicin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 4-hydroxyglucobrassicin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.13.M51
|
–
|
| |
MetaCyc:
RXN-2162
|
|
|
|
4-methoxyindol-3-ylmethyl_isothiocyanate + glutathione <=> (glutathion-S-yl)-4-methoxy-3-indolylmethylisothiocyanate
|
2.5.1
|
–
|
| |
MetaCyc:
RXNQT-4361
|
|
|
|
4-methoxy-3-indolylmethyl_glucosinolate_aglycone <=> 4-methoxyindol-3-ylmethyl_isothiocyanate + sulfate
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4360
|
|
|
|
(glutathion-S-yl)-4-methoxy-3-indolylmethylisothiocyanate + H2O <=> 4-methoxy-3-indolylmethylamine + raphanusamate + L-glutamate + glycine
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4362
|
|
|
|
indolyl-3-methyl-isothiocyanate + glutathione <=> indol-3-ylmethylisothiocyanate-glutathione
|
2.5.1.18
glutathione transferase
|
–
|
| |
MetaCyc:
RXNQT-4363
|
|
|
|
indol-3-ylmethylisothiocyanate-glutathione + H2O <=> indol-3-ylmethylisothiocyanate-[gamma-Glu-Cys} + glycine
|
3.4.17.b
|
–
|
| |
MetaCyc:
RXN-19576
|
|
|
|
indol-3-ylmethylisothiocyanate-L-cysteine <=> 3-(aminomethyl)indole + raphanusamate
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4364
|
|
|
|
indol-3-yl-acetothiohydroxamate-O-sulfonate <=> indolyl-3-methyl-isothiocyanate + sulfate
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4350
|
|
